Collection of Czechoslovak Chemical Communications · 1995 · 27 citations · 0 references
Natural SciencesChemistryCrystal StructureOrganic ChemistrySpectroscopyCoordination ChemistryCoordination NumberCrystal ChemistryMolecular StructureTransition Metal ComplexesCoordination Compound CharacterizationCoordination Geometry DeterminationCoordination PolyhedraSpectroscopic Characterization Of Metal-ligand Bonds
The 13 C and 119 Sn NMR spectra of some mono-n-butyltin(IV) compounds in solution of non-coordinating (CDCl 3 and CD 3 NO 2 ) and coordinating ((CD 3 ) 2 SO and C 5 D 5 N) solvents have been studied. From the values of delta( 119 Sn), 1 J ( 119 Sn, 13 C) and additional 13 C NMR parameters an evaluation of the coordination numbers of the central tin atom and the shapes of coordination polyhedra around the tin atom has been carried out.