Concepedia

An Efficient Synthesis of [Ir(cod)Cl]<sub>2</sub>and Its Reaction with PMe<sub>2</sub>Ph to Give<i>FAC</i>-[IrH(PMe<sub>2</sub>C<sub>6</sub>H<sub>4</sub>)(PMe<sub>2</sub>Ph)<sub>3</sub>]

Robert H. Crabtree, Jennifer M. Quirk, Hugh Felkin, Tauqir Fillebeen-Khan

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry · 1982 · 66 citations · 14 references

DOI

Concepts

Abstract

Abstract An efficient synthesis of [Ir(cod)Cl]2(l) from (NH4)2IrCl6 and aqueous isopropanol giving 92% yield is described. l reacts with PMe2Ph to give fac-[IrH(PMe2C6H4) (PMe2Ph)3]. This is the first case of cyclometalation of PMe2Ph.

References

14

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154. The tautomerism of arene and ditertiary phosphine complexes of ruthenium(0), and the preparation of new types of hydrido-complexes of ruthenium(II)

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Some diolefin complexes of iridium(I) and a trans-influence series for the complexes [IrCl(cod)L]

Robert H. Crabtree, George E. Morris · Journal of Organometallic Chemistry · 1977 · 158 citations

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Formation of large rings, internal metalation reactions, and internal entropy effects

Bernard L. Shaw · Journal of the American Chemical Society · 1975 · 147 citations

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