Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics · 1973 · 107 citations · 0 references
Natural SciencesChemistryPhysicsQuantum ChemistrySpectroscopic AnalysisSpectroscopyAb Initio MethodsCarbonyl ComplexesMolecular Orbital TheoryPhotoelectron SpectroscopyTransition Metal ComplexesX-ray Photoelectron SpectroscopyElectronic Structure AnalysisElectronic Structure Of Metal ComplexesMolecular Orbital AnalysisMultiplet Structure AnalysisTransition Metal CarbonylsValence Electron StructureValence Electronic StructureX-ray Spectra
He(I), He(II) and valence region X-ray photoelectron spectra are reported for the Group VIA hexacarbonyls and are assigned on the basis of published molecular orbital calculations. A pronounced increase in intensity of the first photoelectron band is observed on descending the group, and multiplet structure is clearly discernible on this band in the case of W(CO)6.