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Photoelectron studies of metal carbonyls. Part 2.—The valence region photoelectron spectra of the group VIA hexacarbonyls
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1973
Year
EngineeringChemistryElectronic StructureFirst Photoelectron BandSpectra-structure CorrelationChemical EngineeringElectron SpectroscopyInorganic ChemistryPhotochemistryPhysicsMetal CarbonylsQuantum ChemistryGroup Via HexacarbonylsNatural SciencesSpectroscopyApplied PhysicsMultiplet StructureMain Group ChemistryPhotoelectron Studies
He(I), He(II) and valence region X-ray photoelectron spectra are reported for the Group VIA hexacarbonyls and are assigned on the basis of published molecular orbital calculations. A pronounced increase in intensity of the first photoelectron band is observed on descending the group, and multiplet structure is clearly discernible on this band in the case of W(CO)6.