Japanese Journal of Applied Physics · 2007 · 11 citations · 9 references
Natural SciencesChemical EngineeringChemistryCatalysisReaction EngineeringUltrasoundCatalytic MaterialsCatalytic MechanismsCatalytic Reaction EngineeringCatalytic Reaction KineticsIndustrial Catalytic ProcessesUltrasonicsActivation EnergyActivation Energy DeterminationApparent Activation EnergyCatalyst ActivationCatalyst ActivityTemperature DependenceTemperature Effects On Ester FormationTransesterification
The test temperature dependence of the transesterification of triolein with methanol and a base catalyst (NaOH and KOH) was investigated using a molar ratio of methanol to triolein of 6:1, a catalyst concentration of 1% and a temperature range of 3–50 °C under a low-frequency ultrasonic irradiation condition (40 kHz). It was found that the methyl ester concentration at an irradiation time of 5 min increased with increasing temperature, where it tended to level off at temperatures higher than 20 °C. Furthermore, apparent activation energy was estimated from the relationship between the rate and the reciprocal of temperature.
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Fatty acids methyl esters from vegetable oil by means of ultrasonic energy
Carmen Stavarache, Mircea Vînătoru, Ryo Nishimura et al. · Ultrasonics Sonochemistry · 2004 · 396 citations