European Journal of Organic Chemistry · 2005 · 37 citations · 45 references
Materials ScienceOrganic Material ChemistryEngineeringFundamental Structure–property RelationshipsNatural SciencesDiversity-oriented SynthesisMolecule-based MaterialOrganic ChemistryExtended TetrathiafulvalenesChemistryMolecular EngineeringNovel ChromophoresNovel Donor–acceptor MoleculesTetraethynylethene CoresHeterocycle ChemistrySynthetic ChemistryBiomolecular Engineering
Abstract A selection of new acetylenic building blocks has been prepared and employed for construction of extended tetrathiafulvalenes (TTFs) and novel donor–acceptor molecules based on either diethynylethene (DEE), triethynylethene (TriEE), or tetraethynylethene (TEE) cores. The novel chromophores were studied for their redox, chromophoric, and structural properties, which have provided fundamental structure–property relationships. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)
E. J. Corey, P.L. Fuchs · Tetrahedron Letters · 1972 · 1.6K citations