Concepedia

An approach to the synthesis of gelsemine: the intramolecular reaction of an allylsilane with an acyliminium ion for the synthesis of one of the quaternary centres

Carol Clarke, Ian Fleming, Joseph Fortunak, P. T. Gallagher, Matthew C. Honan, André Mann, Christoph Nübling, Paul R. Raithby, Jens Wolff

Tetrahedron · 1988 · 47 citations · 39 references

DOI

Concepts

References

39

Rules for ring closure

Jack E. Baldwin · Journal of the Chemical Society Chemical Communications · 1976 · 2.2K citations

, , +6

Pyridinium p-toluenesulfonate. A mild and efficient catalyst for the tetrahydropyranylation of alcohols

Masaaki Miyashita, Akira Yoshikoshi, Paul A. Grieco · The Journal of Organic Chemistry · 1977 · 748 citations

, , +7

Methylsulfinyl Carbanion (CH<sub>3</sub>-SO-CH<sub>2</sub><sup>-</sup>). Formation and Applications to Organic Synthesis

E. J. Corey, Michael Chaykovsky · Journal of the American Chemical Society · 1965 · 523 citations

, , +4

Conjugate addition of trimethysilyllithium. A preparation of 3-silyl ketones

W. Clark Still · The Journal of Organic Chemistry · 1976 · 197 citations

, , +7

Prostaglandins and congeners. 20. Synthesis of prostaglandins via conjugate addition of lithium trans-1-alkenyltrialkylalanate reagents. A novel reagent for conjugate 1,4-additions

Karel F. Bernady, M. Brawner Floyd, John F. Poletto et al. · The Journal of Organic Chemistry · 1979 · 169 citations

, , +9