Concepedia

A thermal 6π electrocyclization strategy towards taiwaniaquinoids. First enantiospecific synthesis of (−)-taiwaniaquinone G

Enrique Álvarez‐Manzaneda, Rachid Chahboun, Eduardo Cabrera, Esteban Alvarez, Ali Haı̈dour, Jose Miguel Ramos, Ramón Álvarez-Manzaneda, M. Hmamouchi, Hakima Es‐Samti

Chemical Communications · 2008 · 43 citations · 23 references

DOI

Concepts

Abstract

The first route towards taiwaniaquinoid terpenes bearing an A/B trans-configuration has been developed through a sequence which includes a thermal 6pi electrocyclization.

References

23

Optically pure (4aS)-(+)- or (4aR)-(-)-1,4a-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione and its use in the synthesis of an inhibitor of steroid biosynthesis

Hisahiro Hagiwara, Hisashi Uda · The Journal of Organic Chemistry · 1988 · 181 citations

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The Catalytic Enantioselective, Protecting Group-Free Total Synthesis of (+)-Dichroanone

Ryan M. L. McFadden, Brian M. Stoltz · Journal of the American Chemical Society · 2006 · 169 citations

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Synthesis of Taiwaniaquinoids via Nazarov Triflation

Guangxin Liang, Yue Xu, Ian B. Seiple et al. · Journal of the American Chemical Society · 2006 · 117 citations

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Total Synthesis of (±)-Taiwaniaquinol B via a Domino Intramolecular Friedel−Crafts Acylation/Carbonyl α-<i>tert</i>-Alkylation Reaction

Éric Fillion, Dan Fishlock · Journal of the American Chemical Society · 2005 · 116 citations

, , +12

Uncommon diterpenes with the skeleton of six-five-six fused-rings from Taiwania cryptomerioides

Wang-Hong Lin, Jim‐Min Fang, Yu‐Shia Cheng · Phytochemistry · 1995 · 108 citations

, , +13