Sol-gel derived multiferroic BiFeO3 ceramics with large polarization and weak ferromagnetism

Abstract

Insulating BiFeO3 ceramics of single perovskite phase were prepared by rapid sintering using sol-gel derived fine powders. The ceramics are dense and consist of grains of 2–6μm in diameter. Their leakage current density remains lower than 3.02×10−4A∕cm2 under the poling field below 119kV∕cm. The main conduction mechanism from 15to119kV∕cm is space-charge-limited current relating to oxygen vacancies. The ceramics exhibit a saturated ferroelectric hysteresis loop with a large remanent polarization (2Pr=56μC∕cm2) under the applied field of 180kV∕cm. Weak ferromagnetism with remanent magnetization of 1.5×10−5μB∕Fe is observed at 10K.