Concepedia

Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry

Brian H. Ridgway, K. A. Woerpel

The Journal of Organic Chemistry · 1998 · 121 citations · 5 references

DOI

Concepts

Abstract

Deuterium-labeling experiments demonstrate that the transmetalation step of the Suzuki coupling reaction of alkylboranes and alpha-iodoenones proceeds with retention of stereochemistry.

References

5

Stereochemistry of the cross-coupling reaction of chiral alkylsilanes with aryl triflates: a novel approach to optically active compounds

Yasuo Hatanaka, Tamejiro Hiyama · Journal of the American Chemical Society · 1990 · 155 citations

, , +10

New NMR Spectroscopic Probe of the Absolute Stereoselectivity for Metal-Hydride and Metal-Alkyl Additions to the Carbon−Carbon Double Bond. Demonstration with a Single-Component, Isospecific Ziegler−Natta α-Olefin Polymerization Catalyst

James H. Gilchrist, John E. Bercaw · Journal of the American Chemical Society · 1996 · 56 citations

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Hydrides of bis(cyclopentadienyl)zirconium

B Kautzner, P. C. WAILES, H. Weigold · Journal of the Chemical Society D Chemical Communications · 1969 · 44 citations

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Equilibrium constant for the interconversion of homocub-1(9)-ene and homocuban-9-ylidene

Walter White, Mathew S. Platz, Ning Chen et al. · Journal of the American Chemical Society · 1990 · 25 citations

, , +10

Stereochemistry of the hydroboration reaction

George W. Kabalka, Newell S. Bowman · The Journal of Organic Chemistry · 1973 · 15 citations

, , +5