Concepedia

A chromium(<scp>III</scp>) nickel(<scp>II</scp>) cyanide-bridged ferromagnetic layered structure with corrugated sheets

Sylvie Ferlay, Talal Mallah, Jacqueline Vaissermann, F. Bartolomé, P. Veillet, Michel Verdaguer

Chemical Communications · 1996 · 111 citations · 12 references

DOI

Concepts

Abstract

An infinite stair-like layered ferromagnetic system is obtained from the reaction of K3[CrIII(CN)6] with [NiII-(cyclam)][ClO4]2(cyclam = 1,4,8,11-tetraazacyclotetradecane); a quasi-two-dimensional magnetic behaviour is suggested by the absence of three-dimensional magnetic order down to 2 K.

References

12

Photoinduced Magnetization of a Cobalt-Iron Cyanide

Osamu Sato, Tomokazu Iyoda, Akira Fujishima et al. · Science · 1996 · 1.8K citations

, , +20

A room-temperature organometallic magnet based on Prussian blue

Sylvie Ferlay, Talal Mallah, R. Ouahès et al. · Nature · 1995 · 1.5K citations

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High- <i>T</i> <sub>c</sub> Molecular-Based Magnets: Ferrimagnetic Mixed-Valence Chromium(III)-Chromium(II) Cyanides with <i>T</i> <sub>c</sub> at 240 and 190 Kelvin

Talal Mallah, S. Thiébaut, Michel Verdaguer et al. · Science · 1993 · 817 citations

High-Temperature Molecular Magnets Based on Cyanovanadate Building Blocks: Spontaneous Magnetization at 230 K

William R. Entley, Gregory S. Girolami · Science · 1995 · 622 citations

Electrochemically Tunable Magnetic Phase Transition in a High- <i>T</i> <sub>c</sub> Chromium Cyanide Thin Film

Osamu Sato, Tomokazu Iyoda, Akira Fujishima et al. · Science · 1996 · 591 citations

, , +18