A chromium(<scp>III</scp>) nickel(<scp>II</scp>) cyanide-bridged ferromagnetic layered structure with corrugated sheets

Abstract

An infinite stair-like layered ferromagnetic system is obtained from the reaction of K3[CrIII(CN)6] with [NiII-(cyclam)][ClO4]2(cyclam = 1,4,8,11-tetraazacyclotetradecane); a quasi-two-dimensional magnetic behaviour is suggested by the absence of three-dimensional magnetic order down to 2 K.