Chemical Communications · 2013 · 50 citations · 33 references
Materials ScienceInorganic ChemistryChemical EngineeringLi3 CorroleEngineeringInorganic MaterialCoordination ComplexFree Base CorroleChemistryLanthanide CorrolesInorganic SynthesisInorganic Compound
The first examples of lanthanide corroles are prepared by two synthetic routes. (Mes2(p-OMePh)corrole)La·4.5DME (1·4.5DME) and (Mes2(p-OMePh)corrole)Tb·4DME (2·4DME) are prepared from the free base corrole and Ln((NSiMe3)2)3, while (Mes2(p-OMePh)corrole)Gd·TACNMe3 (3·TACNMe3) is prepared by metathesis of the recently reported Li3 corrole and GdCl3.
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