Preparation Process and Upconversion Luminescence of Er³⁺-Doped Glass Ceramics Containing Ba₂LaF₇ Nanocrystals

Abstract

The preparation process and upconversion luminescence of the Er(3+)-doped glass ceramics containing Ba(2)LaF(7) nanocrystals were investigated. The formation of Ba(2)LaF(7) nanocrystals in the glass ceramics was confirmed by X-ray diffraction. Er(3+)-doped glass ceramics containing Ba(2)LaF(7) nanocrystals exhibited highly efficient upconversion luminescence in comparison with glasses. With the increase of heat treatment temperature the upconversion luminescence intensity increased gradually. The composition of glasses was also found to have significant influence on the crystallization process of glass ceramics. The mixture of Ba(2)LaF(7) and La(2)O(3) nanocrystals and the mixture of La(2)F(3) and La(2)O(3) nanocrystals in the glass ceramics could be obtained by controlling different compositions of glasses. The upconversion luminescence intensity also varied significantly with different nanocrystals in the glass ceramics.