Journal of Physics B Atomic Molecular and Optical Physics · 1993 · 78 citations · 10 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryMaterials ChemistryPhysical ChemistryCoordination ChemistryCoordination NumberCrystal SymmetryCrystallographyX-ray CrystallographyX-ray DiffractionBonding In Coordination CompoundsCoordination Compound CharacterizationCoordination Number AnalysisCoordination Number DeterminationOctahedral CoordinationTetrahedral CoordinationX-ray Diffraction DetectionX-ray Structure Determination
The effects of changes in coordination number on Kbeta/Kalpha x-ray intensity ratio have been studied experimentally. The Kbeta/Kalpha x-ray intensity ratios for both pure Cr, Mn and Cu and their various chemical compounds with tetrahedral and octahedral symmetry are investigated using a Ge(Li) detector. The measured results indicate that the Kbeta/Kalpha ratios for compounds with tetrahedral symmetry are in general larger than those with octahedral symmetry. The obtained Kbeta/Kalpha x-ray intensity ratios are comparable with both previous published experimental and theoretical results.
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