Simultaneous Multimode Pressure-Induced Frequency-Shift Measurements in Shock-Compressed Organic Liquid Mixtures by Use of Reflected Broadband Coherent Anti-Stokes Raman Scattering

Abstract

Reflected broadband (multichannel) coherent anti-Stokes Raman scattering was used to measure the ring-breathing-mode vibrational frequencies of neat liquid benzene, neat liquid deuterated benzene (benzene-${d}_{6}$), and mixtures of these under shock compression to pressures up to 1.53 GPa. The pressure-induced frequency shifts determined for neat benzene agree with those obtained previously by use of backward stimulated Raman scattering. Evidence for nearest-neighbor effects on the vibrational frequency shifts is presented.