Infrared Spectra of Matrix-Isolated Acetic Acid Monomers

Abstract

Infrared spectra of monomeric acetic acids [CH3COOH(D) and CD3COOH(D)] isolated in Ar and N2 matrices near 4°K are reported. A large anharmonic potential-energy contribution is evident from the observed isotopic frequency shifts. It is proposed that this arises primarily from the double-minimum potential-energy curve for tunneling of the H atom between O atoms via the COH angle bending coordinate. In all cases, important coupling between the COH angle bending and C–O stretching coordinates is observed, with a strong addition of CD3 (umbrella) angle deformation in the case of CD3COOH. Exceptional matrix effects are observed for the coupled vibrations of the –OH molecules. A complete assignment is proposed for these acetic acids on the basis of the new data. As additional supporting evidence, the spectrum of matrix-isolated CH3COF and of acetic acid vapor at low pressure and long path length are reported.