Journal of the American Chemical Society · 2013 · 2.1K citations · 23 references
Natural SciencesMaterials EngineeringMaterials ScienceElectrochemical EngineeringEnergy MaterialsMaterials ChemistryAnode MaterialsBattery MaterialsBattery TechnologyElectrochemical CellsElectrode MaterialsEnergy Storage MaterialsEtchingLithium-ion BatteriesLithium-ion Battery Anode MaterialsLithium-ion Battery ChemistryLithium-ion Battery Electrodes Based On Metal OxidesLithium-ion Battery MaterialsNanostructured Battery MaterialsSelective Etching
New two-dimensional niobium and vanadium carbides have been synthesized by selective etching, at room temperature, of Al from Nb2AlC and V2AlC, respectively. These new matrials are promising electrode materials for Li-ion batteries, demonstrating good capability to handle high charge-discharge rates. Reversible capacities of 170 and 260 mA·h·g(-1) at 1 C, and 110 and 125 mA·h·g(-1) at 10 C were obtained for Nb2C and V2C-based electrodes, respectively.
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