Concepedia

<i>aci</i>‐nitromethane —generated and characterized by neutralization reionization mass spectrometry

Helge Egsgaard, Lars Carlsen, Helena Florêncio, Thomas Drewello, Helmut Schwarz

Berichte der Bunsengesellschaft für physikalische Chemie · 1989 · 26 citations · 18 references

DOI

Concepts

Abstract

Abstract Neutral gaseous aci ‐nitromethane has been generated and characterized by neutralization/reionization mass spectrometry (NRMS). Decomposition and isomerization patterns have been established based on studies of the corresponding nitromethane and methyl nitrite isomers in combination with appropriate deuterium labelling experiments. A comparison of the isomeric CH 2 NO(OH), CH 3 NO 2 and CH 3 ONO neutrals as well as radical cations is presented.

References

18

The Generation and Characterization of Molecules by Neutralization‐Reionization Mass Spectrometry (NRMS). New Analytical Methods (33)

Johan K. Terlouw, Helmut Schwarz · Angewandte Chemie International Edition in English · 1987 · 231 citations

, , +17

Ab initio study of rearrangements on the nitromethane potential energy surface

Michael L. McKee · Journal of the American Chemical Society · 1986 · 108 citations

, , +19

Ground states of molecules. 65. Thermolysis of molecules containing NO2 groups

Michael J. S. Dewar, James Ritchie, Jack Alster · The Journal of Organic Chemistry · 1985 · 104 citations

, , +19

Thermolysis of NH<sub>4</sub>HCO<sub>3</sub>—A Simple Route to the Formation of Free Carbonic Acid (H<sub>2</sub>CO<sub>3</sub>) in the Gas Phase

Johan K. Terlouw, Carlito B. Lebrilla, Helmut Schwarz · Angewandte Chemie International Edition in English · 1987 · 89 citations

, , +13

The generation of triplet methoxy cations

Peter C. Burgers, John Holmes · Organic Mass Spectrometry · 1984 · 64 citations

, , +16