Thermal stability of epitaxial Mn5Ge3 and carbon-doped Mn5Ge3 films

A. Spiesser, Vinh Le Thanh, Sylvain Bertaina, Lisa Michez

Applied Physics Letters · 2011 · 32 citations · 19 references

Concepts

Abstract

The thermal stability of epitaxial Mn5Ge3 and carbon-doped Mn5Ge3 films was investigated by combining structural and magnetic characterizations. It is shown that ferromagnetic Mn5Ge3 films transform into antiferromagnetic Mn11Ge8 upon post-annealing at 650 °C whereas carbon-doped Mn5Ge3 conserves its ferromagnetism up to 850 °C. The magnetic properties of Mn5Ge3 (Curie temperature, magnetization at saturation, and magnetic moment per Mn atom) are found to undergo a reversible transition upon carbon doping and its extraction during thermal annealing. The stability of carbon-doped Mn5Ge3 films will be discussed in terms of carbon filling of interstitial sites of Mn5Ge3, which prevents Ge diffusion from the substrate.

References

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