Publication | Closed Access
Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex
115
Citations
17
References
2004
Year
Inorganic ChemistrySolvent-dependent InteractionEngineering14-Electron RhNatural SciencesCoordination ComplexMolecular BiologyRh−nhc Complex LeadingDouble C−h ActivationChloride LigandOrganometallic CatalysisMolecular ComplexChemistryInorganic SynthesisBiomolecular EngineeringInorganic Compound
The solvent-dependent interaction of ItBu with a Rh(I)-olefin complex leads to the isolation of two precursors en route to a unique double cyclometalation process. Abstraction of the chloride ligand from the resulting complex enables the isolation of a "bare" 14-electron Rh(III) complex.
| Year | Citations | |
|---|---|---|
Page 1
Page 1