Journal of Analytical Atomic Spectrometry · 2014 · 19 citations · 7 references
Natural SciencesArt HistoryChemistryElemental AnalysisPaintingSpectroscopyX-ray Fluorescence AnalysisX-ray Photoelectron SpectroscopyMicro X-ray FluorescencePainting HistoryPainting Materials AnalysisX-ray Fluorescence Spectroscopy
There exist several very similar looking versions of the painting ‘The Reading Hermit’, all allegedly painted by Rembrandt Harmenszoon van Rijn (approx. in ∼1630 A.D., Leiden). The classification of Rembrandt's paintings, which were produced by Rembrandt himself, in his academy by his students and the ones being mere copies is a crucial and difficult task. We gathered background evidence and performed elemental analyses by non-destructive micro-X-ray fluorescence (micro-XRF) in order to elucidate the painting's provenance. Elemental distributions of Ca, Mn, Fe and Cu show that the painting was presumably changed during the painting process, which indicates, together with neutron autoradiography (NAR) investigations, that this version of ‘The Reading Hermit’ is not a copy.
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Use of microscopic XRF for non-destructive analysis in art and archaeometry
Koen Janssens, G. Vittiglio, I. Deraedt et al. · X-Ray Spectrometry · 2000 · 245 citations
Kouichi Tsuji, Kazuhiko Nakano, Yoshio Takahashi et al. · Analytical Chemistry · 2011 · 47 citations