Concepedia

Metal dialkyl diselenophosphates:1 a rare example of co-crystallization with clusters, Ag8(μ8-Se)[Se2P(OPri)2]6 and Ag6[Se2P(OPri)2]6, superimposing in a trigonal lattice†

C. W. Liu, Iu-Jie Shang, Ju-Chung Wang, Tai‐Chiun Keng

Chemical Communications · 1999 · 52 citations · 14 references

Concepts

Materials ScienceInorganic ChemistryCrystal StructureCluster ScienceEngineeringRemarkable Co-crystallizationCluster ChemistryFunctional MaterialsMetal Dialkyl Diselenophosphates:1Trigonal Lattice†ChemistryNeutral ClustersTrigonal LatticeCrystal FormationInorganic MaterialCrystallographyCrystal Structure DesignRare Example

Abstract

A remarkable co-crystallization in which two neutral clusters, Ag8(Se)[Se2P(OPri)2]6 and Ag6[Se2P(OPri)2]6, superimpose along the three-fold axis in the trigonal lattice and share a common Ag6[Se2P(OPri)2]6 unit, is reported.

References

14

Stereochemical aspects of phosphor-1,1-dithiolato metal complexes (dithiophosphates, dithiophosphinates): Coordination patterns, molecular structures and supramolecular associations—I

Ionel Haiduc, D. Bryan Sowerby, Shao‐Fang Lu · Polyhedron · 1995 · 237 citations

Inorganic Chemistry, Coordination Patterns, Engineering +10

Syntheses and Structural Characterizations of Two New Cu-S Clusters of Dialkyl Dithiophosphates: A Sulfide-Centered CuI8 Cube, {Cu8[S2P(OiPr)2]6(.mu.8-S)}, and a Distorted Octahedral {Cu6[S2P(OEt)2]6.cntdot.2H2O} Cluster

C. W. Liu, Theron Stubbs, Richard J. Staples et al. · Journal of the American Chemical Society · 1995 · 94 citations

Materials Science, Inorganic Chemistry, Sulfide-centered Cui8 Cube +11

[Au<sub>2</sub>Ag<sub>4</sub>L<sub>4</sub>]<sup>2⊖</sup>, [Au<sub>2</sub>Cu<sub>4</sub>L<sub>4</sub>]<sup>2⊖</sup>, [Au<sub>3</sub>Cu<sub>3</sub>L<sub>4</sub>]<sup>2⊖</sup>, [Cu<sub>4</sub>L<sub>3</sub>]<sup>2⊖</sup>, and [Ag<sub>9</sub>L<sub>6</sub>]<sup>3⊖</sup> (L = ethane‐1,2‐dithiolate)—Novel Homoleptic Complexes of the Coinage Metals, including the First Heteronuclear Metal Thiolates

Gerald Henkel, Bernt Krebs, P. Betz et al. · Angewandte Chemie International Edition in English · 1988 · 62 citations

Crystal Structure, Engineering, Molecular Biology +16

New Methods of Resolution and Enrichment of Enantiomeric Excesses of 1,1‘-Bi-2-naphthol

Lakshmanan Venkatraman, K. R. Justin Thomas · The Journal of Organic Chemistry · 1997 · 56 citations

Engineering, Organic Chemistry, Chemistry +17

Tetrahedral, octahedral, cubal and centered cubal dithiolate clusters and cages of Cu(i) and Ag(i)

John P. Fackler, Richard J. Staples, C. W. Liu et al. · Pure and Applied Chemistry · 1998 · 54 citations · Full text

Materials Science, Inorganic Chemistry, Cluster Science +7