Concepedia

Novel π-complexes of divalent silicon: mixed substituted neutral sandwich compounds and the half-sandwich cation (<sup>i</sup>Pr<sub>5</sub>C<sub>5</sub>)Si<sup>+</sup>

Peter Jutzi, Andreas Mix, Beate Neumann, Britta Rummel, Hans‐Georg Stammler

Chemical Communications · 2006 · 50 citations · 6 references

DOI

Concepts

Abstract

The pentamethylcyclopentadienylsilicon(II) cation, Me5C5Si+, opens up access to novel silicocene derivatives; the penta-iso-propylcyclopentadienylsilicon(II) cation, iPr5C5Si+, is obtained by reaction of the mixed silicocene (iPr5C5)(Me5C5)Si with H(OEt2)2+ Al[OC(CF3)3]4-.

References

6

The (Me <sub>5</sub> C <sub>5</sub> )Si <sup>+</sup> Cation: A Stable Derivative of HSi <sup>+</sup>

Peter Jutzi, Andreas Mix, Britta Rummel et al. · Science · 2004 · 217 citations

, , +8

Perfluorinated Alkoxyaluminate Salts of Cationic Brønsted Acids: Synthesis, Structure, and Characterization of [H(OEt<sub>2</sub>)<sub>2</sub>][Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>] and[H(THF)<sub>2</sub>][Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]

Ingo Krossing, Andreas Reisinger · European Journal of Inorganic Chemistry · 2005 · 75 citations · Full text

, , +6

[(π‐Me<sub>5</sub>C<sub>5</sub>)<sub>2</sub>SiH]<sup>+</sup>—A Novel Silyl Cation

Peter Jutzi, E. A. Bunte · Angewandte Chemie International Edition in English · 1992 · 49 citations

, , +7

Mono‐ and Bis(pentaisopropylcyclopentadienyl) Cobalt and Rhodium Sandwich Complexes and Other Decabranched Cyclopentadienyl Complexes

Dirk Buchholz, Bruno Gloaguen, Jean‐Luc Fillaut et al. · Chemistry - A European Journal · 1995 · 37 citations

, , +10

The Nature of Protonated Decamethylsilicocene, (Me<sub>5</sub>C<sub>5</sub>)<sub>2</sub>Si<sup>+</sup>H

Thomas Müller, Peter Jutzi, T. Kuhler · Organometallics · 2001 · 17 citations

, , +14