Journal of the American Chemical Society · 2003 · 17 citations · 18 references
Natural SciencesChemistryPhysicsOrganic ChemistryPhysical ChemistrySpectroscopyHeterocyclic ChemistryMolecular Orbital TheoryMolecular SymmetryRadical ReactionsReaction MechanismsReaction PathwaysAromatic Electronic EffectsElectronic Control Of ReactivityElectronic Structure EffectsHammett Electronic EffectsHeterocyclic ReactivityRadical Reaction MechanismsStructure-reactivity RelationshipsTriplet State Chemistry
A gas-phase study of the radical reactivities of didehydroarenes with a 1,4-relationship reveals that electronic effects (due to singlet-triplet state splittings) can be offset by polar effects.
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Free radicals in organic chemistry
W. A. PRYOR · Free Radical Biology and Medicine · 1996 · 486 citations