Concepedia

Platinum catalysed 1,4-diboration of α,β-unsaturated ketones

Yvonne G. Lawson, M. J. Gerald Lesley, Nicholas C. Norman, Craig R. Rice, Yvonne G. Lawson, Todd B. Marder

Chemical Communications · 1997 · 149 citations · 8 references

DOI

Concepts

Abstract

Diborane(4) compounds react with α,β-unsaturated ketones to give the 1,4-addition product in the presence of a platinum catalyst at 80 °C.

References

8

Hydroborations catalysed by transition metal complexes

I. P. Beletskaya, Andrew Pelter · Tetrahedron · 1997 · 618 citations

, , +9

Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo)diborons:  An Efficient and Convenient Approach to <i>cis</i>-Bis(boryl)alkenes

Tatsuo Ishiyama, Nobuo Matsuda, Miki Murata et al. · Organometallics · 1996 · 321 citations

, , +16

Transition Metal Catalyzed Diboration of Vinylarenes

R.T.K. Baker, Paul Nguyen, Todd B. Marder et al. · Angewandte Chemie International Edition in English · 1995 · 257 citations

, , +10

Reactivity of Organoplatinum Complexes with C6H4O2B-BO2C6H4: Syntheses of a Platinum Diboryl Complex with, and without, Metathesis of Boron-Boron and Metal-Carbon Bonds

Carl N. Iverson, Milton R. Smith · Journal of the American Chemical Society · 1995 · 192 citations

, , +17

Mechanistic Investigation of Stoichiometric Alkyne Insertion into Pt−B Bonds and Related Chemistry Bearing on the Catalytic Diborylation of Alkynes Mediated by Platinum(II) Diboryl Complexes

Carl N. Iverson, Milton R. Smith · Organometallics · 1996 · 164 citations

, , +16