Angewandte Chemie International Edition in English · 1995 · 257 citations · 16 references
Natural SciencesChemistryCatalysisOrganic ChemistryAlkyne ComplexesHeterocycle SynthesisHeterocyclic ChemistryOrganic SynthesisTransition Metal ChemistryElectron-rich ComplexesTransition Metal-catalyzed SynthesisTransition-metal-catalyzed FunctionalizationTransition-metal-catalyzed Heterocycle Synthesis
An electron-rich phosphanegold complex is used in the first catalyzed diboration of alkenes. The reaction of diborane 1 with alkene 2 in the presence of [AuCl(PEt3)] and ethane-1,2-diylbis(dicyclohexylphosphane) yields exclusively the 1,2-bis(boronate) ester 3.
16
Platinum(0)-catalyzed diboration of alkynes
Tatsuo Ishiyama, Nobuo Matsuda, Norio Miyaura et al. · Journal of the American Chemical Society · 1993 · 451 citations
Carl N. Iverson, Milton R. Smith · Journal of the American Chemical Society · 1995 · 192 citations