Science · 1975 · 310 citations · 18 references
PharmacyMaterials ScienceHeat TransferLyophilizationThermal AnalysisHeat Transfer In Freeze-dryingPrinciples Of Freeze-dryingFreezing Onset TemperatureRepresentative SamplesSubcoolingSupercooled Liquid WaterSupercooled Water ProcessesSupercritical Fluid BehaviorSupercritical Fluids
The temperature at which "clean" supercooled water freezes has been determined as a function of pressure up to 3 kilobars, using a differential thermal analysis technique on subdivided water samples. The supercooling limit of such samples, -38 degrees C at normal pressure, is lowered by initial increase of pressure, reaching a minimum value of -92 degrees C at 2.00 kilobars.
18
The structure of vitreous silica
R. L. Mozzi, Β. E. Warren · Journal of Applied Crystallography · 1969 · 1.4K citations
Self-Diffusion in Liquid Water to −31°C
K.T. Gillen, D. C. Douglass, Michael Hoch · The Journal of Chemical Physics · 1972 · 291 citations
Clustering in supercooled water
Don H. Rasmussen, A. P. Mackenzie · The Journal of Chemical Physics · 1973 · 179 citations
Natural Sciences, Chemistry, Physics +16