Fuel Science and Technology International · 1988 · 10 citations · 11 references
Natural SciencesChemical EngineeringChemistryCatalysisPhase TransformationsPhysical ChemistryCatalyst CharacterizationCatalyst SynthesisCatalytic MaterialsCatalytic Reaction EngineeringPhase DiagramsPhase IdentificationCatalyst Active SitesMethanol Synthesis CatalysisPowder DiffractionPowder Diffraction AnalysisPowder X-ray DiffractionTransition Metal Catalysts
ABSTRACT An attempt has been made to identify the phases present in the active catalyst for liquid phase methanol synthesis. X-ray powder diffraction was used to identify the phases. Only metallic Cu was detected, while no Cu species was found to be present. A significant amount of ZnCO3 was found to be present in catalysts which had been subjected to high partial pressures of C02. This fact has hitherto not been reported in literature. Some speculations about the effect of ZnCO3 on the life of the catalyst are made.
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Yasuaki Okamoto, Kiyotaka Fukino, Toshinobu Imanaka et al. · The Journal of Physical Chemistry · 1983 · 136 citations
Studies on the chemical state of Cu during methanol synthesis
T.H. Fleisch · Journal of Catalysis · 1984 · 132 citations
The chemical state of copper during methanol synthesis
G.C. Chinchen · Journal of Catalysis · 1986 · 115 citations