Concepedia

p-Toluenesulphonic acid-promoted, I<sub>2</sub>-catalysed sulphenylation of pyrazolones with aryl sulphonyl hydrazides

Xia Zhao, Lipeng Zhang, Tianjiao Li, Guiyan Liu, Haomeng Wang, Kui Lu

Chemical Communications · 2014 · 116 citations · 59 references

DOI

Concepts

Abstract

Aryl pyrazolone thioethers were synthesized via the I2-catalysed cross-coupling of pyrazolones with aryl sulphonyl hydrazides in the presence of p-toluenesulphonic acid, which has been proposed to promote the reaction by facilitating the decomposition of sulphonyl hydrazides.

References

59

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I. P. Beletskaya, Andrei V. Cheprakov · Coordination Chemistry Reviews · 2004 · 1.5K citations

, , +7

A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols

Manuel A. Fernández‐Rodríguez, Qilong Shen, John F. Hartwig · Journal of the American Chemical Society · 2006 · 707 citations

, , +13

Iron‐Catalyzed S‐Arylation of Thiols with Aryl Iodides

Arkaitz Correa, Mónica Carril, Carsten Bolm · Angewandte Chemie International Edition · 2008 · 548 citations

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Cobalt-Catalyzed Aryl−Sulfur Bond Formation

Ying‐Chieh Wong, Thiruvellore Thatai Jayanth, Chien‐Hong Cheng · Organic Letters · 2006 · 453 citations

, , +12

The First Phosphine Oxide Ligand Precursors for Transition Metal Catalyzed Cross-Coupling Reactions: C−C, C−N, and C−S Bond Formation on Unactivated Aryl Chlorides

George Y. Li · Angewandte Chemie International Edition · 2001 · 420 citations

, , +15