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Chemoenzymatic and Enantiodivergent Routes to Highly Functionalised Steroidal Nuclei
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1999
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EngineeringMolecular BiologyOrganic ChemistryHeterocycle ChemistryEnantiopure Cis-1,2-dihydrocatechol 2Stereoselective SynthesisCompound 1Steroid MetabolismBiochemistryOligonucleotideDna ReplicationEnantiodivergent RoutesAsymmetric CatalysisEnantioselective SynthesisBiomolecular EngineeringChromatinHeterocyclicDiels-alder CycloadditionNatural Sciences
The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).