Physical Review Letters · 1997 · 277 citations · 20 references
Natural SciencesPhysicsCondensed Matter PhysicsQuantum MechanicsSolid State PhysicsElectron CorrelationMagnetic Properties Of SolidsMagnetism In SolidsPerovskite MaterialsPhase TransitionsStrongly Correlated Electron SystemsLong-range OrderMagnetic PerovskitesMagnetic Phase DiagramMulticritical PointsQuantum MagnetismQuantum Spin LiquidsSpin-orbital CouplingSpin-orbital Formulations
We have studied the phase diagram and excitations of the spin-orbital model derived for a three-dimensional perovskite lattice, as in ${\mathrm{KCuF}}_{3}$. The results demonstrate that the orbital degeneracy drastically increases quantum fluctuations and suppresses the classical long-range order near the multicritical point in the mean-field phase diagram. This indicates the presence of a quantum liquid state, and we present explicit evidence for valence bond type correlations in three dimensions.
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The Jahn-Teller effect and magnetism: transition metal compounds
D. I. Khomskiǐ · Soviet Physics Uspekhi · 1982 · 1.3K citations
Natural Sciences, Chemistry, Physics +17