JOURNAL OF CHEMICAL ENGINEERING OF JAPAN · 1983 · 16 citations · 0 references
Natural SciencesChemical EngineeringChemistryPhysical ChemistryThermal AnalysisThermodynamicsChemical ThermodynamicsEquations Of StatePhase DiagramsPhase EquilibriaPhase EquilibriumPhase TransitionsCritical PointsHigh-pressure Equation Of StateHigh-pressure Phase RelationsPhase Diagram AnalysisPhase Equilibria At High PressureRedlich-kwong Equation Of StateSoave-redlich-kwong Equation Of StateTemperature Effects On Phase Behavior
Isothermal phase equilibria for the system methanol-ethylene were measured at 25°C and 40°C by a static method. At each temperature, an invisible boundary in a high-pressure equilibrium region was found by gas chromatographic analysis. For studying the phase behavior of the methanol-ethylene system, the critical loci for the system were estimated by using the Soave-Redlich-Kwong equation of state. The calculation shows that an isothermal phase equilibrium of the methanol-ethylene system exhibits one to three critical points.