Solution-processed pentacene quantum-dot polymeric nanocomposite for infrared photodetection

Abstract

An organic/inorganic polymeric nanocomposite thin film device, consisting of poly-N-vinyl carbazole as host matrix, lead selenide quantum dots as photosensitizer, and the organic semiconductor pentacene as a conductivity booster, is fabricated. Because of the inherent insolubility of pentacene, it is incorporated in the form of a soluble precursor which is made to undergo thermal conversion into pentacene. The device exhibits dramatic enhancement of infrared photocurrent due to pentacene. Efficient photogeneration of carriers coupled with enhanced conductance results in high photoconductive quantum efficiency.