Simultaneous Effect of Doppler and Foreign Gas Broadening on Spectral Lines

Abstract

By using the classical Fourier integral theory, an expression is given for the shape of a spectral line, broadened by phase changes due to collisions and by the actual changes in velocity of the emitting particles resulting from collisions. The result is not a simple Voigt-type folding of an exponential into a dispersion distribution; it exhibits the contraction noted by Dicke and leads to the usual formulas when the time interval between path-deflecting or phase-disturbing collisions becomes very great.