Chemical Communications · 2009 · 30 citations · 32 references
Natural SciencesChemistryCatalysisOrganic ChemistryOrganometallic ChemistryCoordination ChemistryHeterocycle SynthesisOrganometallic SynthesisAlkylation ReactionsCatalyst MechanismsCopper-catalyzed CouplingGrignard Reagent SynthesisOrganometallic Catalyst DesignTransition Metal-catalyzed Synthesis
A novel acyclic diaminocarbene-copper complex appears to be generated from a chloroamidinium salt and Cu(I)-thiophenecarboxylate in the presence of Grignard reagent based on (13)C NMR studies and is a highly efficient catalyst for S(N)2'-allylic alkylation.
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Roger W. Alder, Paul R. Allen, Martin J. Murray et al. · Angewandte Chemie International Edition in English · 1996 · 305 citations