Publication | Closed Access
(NHC)Cu<sup>I</sup> (NHC = N-Heterocyclic Carbene) Complexes as Efficient Catalysts for the Reduction of Carbonyl Compounds
302
Citations
13
References
2004
Year
Inorganic ChemistryChemical EngineeringCarbonyl CompoundsSalt SystemEngineeringNovel OrganocatalystsCoordination ComplexCatalytic SynthesisCucl ComplexesOrganic ChemistryOrganometallic CatalysisCatalysisMolecular CatalysisChemistryEfficient CatalystsInorganic SynthesisCatalyst Precursor System
The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.
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