Nanostructure fabrication using block copolymers

Ian W. Hamley

Nanotechnology · 2003 · 768 citations · 161 references

Concepts

TL;DR

Recent advances in block copolymer self‑assembly enable the creation of morphologies that can template nanostructures, with applications ranging from mesoporous materials to photonic crystals. The authors describe using block copolymer film masks to pattern semiconductor surfaces and magnetic domains, employing micelle nanoreactors to synthesize and arrange metal and semiconductor nanoparticles, and outlining strategies for designing nanocapsules.

Abstract

A brief overview is provided of recent developments in the use of block copolymer self-assembly to create morphologies that may be used to template the fabrication of nanostructures in other materials. The patterning of semiconductor surfaces using block copolymer film masks and the production of high-density arrays of magnetic domains are discussed. The use of block copolymer micelles as 'nanoreactors' to prepare metal and semiconductor nanoparticles is considered, and methods to pattern nanoparticles are highlighted. A number of approaches to design nanocapsules are summarized. Finally, applications of bulk nanostructures to make mesoporous materials with controlled pore structures and sizes, or to create photonic crystals, are discussed.

References

161