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Studies on Metal Carbonate Equilibria. 22. A Coulometric Study of the Uranium(VI)--Carbonate System, the Composition of the Mixed Hydroxide Carbonate Species.

Ingmar Grenthe, Bo Lagerman, Rita G. Hazell, Fredrik Lindgren, Michael Sjöstróm, Svante Wold, George W. Francis, Britt Karlsson

Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry · 1991 · 26 citations · 0 references

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Abstract

Complex formation in the uranium(IV)-H 2 O-CO 2 (g) system has been studied at 25°C in a 0.50 m NaClO 4 medium. The experimental method was potentiometry (H + -measurements), using coulometry to change the total concentration of hydrogen ions