The Journal of Chemical Physics · 1968 · 14 citations · 2 references
Natural SciencesChemistryPhysicsMolecular PhysicsQuantum ChemistryAb Initio MethodsElectron CorrelationExchange InteractionsHartree-fock TheoryMolecular Orbital TheorySpin-orbit CouplingElectron Correlation EnergySpin-orbit Coupling EffectsSpin-orbit Splitting
The spin–orbit splitting factors for various terms of positive ions of Cr, Mn, and Fe have been evaluated from existing analytical Hartree–Fock functions. The agreement with the experimental values, whenever available, is satisfactory.
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S. Goudsmit, C. J. Humphreys · Physical Review · 1928 · 19 citations