Inorganic Chemistry · 2004 · 37 citations · 32 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistrySpectroscopyCoordination ChemistryCrystal ChemistryIntermolecular InteractionsMagnetism Of Inorganic CompoundsMetal-ligand BondingTransition Metal ComplexesHydrogen BondingHydrogen Bonding InteractionsIntermolecular Metal-ligand InteractionsMagnetic PropertiesMagnetic Properties Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesSingle Crystal AnalysisSingle-crystal X-ray Diffraction
A novel complex, [[CoAu2(CN)4(NITpPy)2(H2O)2]]n, 1, containing the cobalt(II) ion, dicyanoaurate(I) anion, and nitronyl nitroxide radical building blocks, has been prepared and structurally characterized by single-crystal X-ray analysis. The structure of complex 1 illustrates that aurophilicity and hydrogen bonding interactions increase dimensionality, generating a 2-D interdigitating system. The spectroscopic and magnetic properties have been investigated.
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Makoto Fujita, Yoon Jung Kwon, Satoru Washizu et al. · Journal of the American Chemical Society · 1994 · 2.4K citations