Chemistry Letters · 1978 · 117 citations · 6 references
Natural SciencesMaterials SciencePhysicsMaterials ChemistryPolymer ChemistrySpectroscopyConducting PolymersConductive PolymersOrganic SemiconductorsPolymer Physical ChemistryPolymer PhysicsRaman SpectroscopyBond LengthsConductivity In PolymersConjugated Polymer StructuresDoped Conducting PolymersPolyacetyleneRaman Spectra
Abstract The Raman spectra of conductive polyacetylene-iodine complexes and their parent polymers have been studied. The trans-rich polyacetylene film contains trans segments of various lengths while the cis-rich polyacetylene film is composed of relatively long cis sequences. The doped iodine takes either the form of (I3−)x or I5−.
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