Concepedia

Preparation and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation: modulated chemistry resulting from the use of soft and hard tripodal ligands

P.A. Slavin, J. Reglinski, Mark D. Spicer, Alan R. Kennedy

Journal of the Chemical Society Dalton Transactions · 2000 · 44 citations · 6 references

DOI

Concepts

Abstract

The synthesis and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation is reported, in which the thallium ion is co-ordinated by six sulfur thione donors in a regular octahedral environment.

References

6

Modeling the Catalytic Site of Liver Alcohol Dehydrogenase:  Synthesis and Structural Characterization of a [Bis(thioimidazolyl)(pyrazolyl)hydroborato]zinc Complex, [HB(tim<sup>Me</sup>)<sub>2</sub>pz]ZnI

C. Kimblin, T. Hascall, Gerard Parkin · Inorganic Chemistry · 1997 · 170 citations

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Structural Consequences of the Use of Hard and Soft Tripodal Ligands during Metathesis Reactions:  Synthesis of the [Bis(hydrotris(methimazolyl)borato]bismuth(III) [Bis(hydrotris(pyrazolyl)borato]sodiate

J. Reglinski, Mark D. Spicer, Mark M. Garner et al. · Journal of the American Chemical Society · 1999 · 82 citations

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Phenyltris((<i>tert</i>-butylthio)methyl)borate:  A Second Generation S<sub>3</sub><sup>-</sup> Ligand That Enforces Tetrahedral Coordination

P.J. Schebler, Charles G. Riordan, Ilia A. Guzei et al. · Inorganic Chemistry · 1998 · 80 citations

, , +14

Poly(methylthiomethyl)Borates: A New Class of Sulfur-Rich Ligands for Metal Ions

Pinghua Ge, Brian S. Haggerty, Arnold L. Rheingold et al. · Journal of the American Chemical Society · 1994 · 76 citations

, , +8

Crystal and molecular structure and the kinetics of ligand exchange of tris(N,N-dimethyldithiocarbamato)thallium(III)

Harmon B. Abrahamson, J. R. Heiman, L. H. Pignolet · Inorganic Chemistry · 1975 · 34 citations

, , +10