Exploration Tools for Linked Porphyry and Epithermal Deposits: Example from the Mankayan Intrusion-Centered Cu-Au District, Luzon, Philippines*

Abstract

<p>The Mankayan mineral district of northern Luzon, Philippines, hosts several significant ore deposits andprospects of various types within an area of ~25 km2, including the Far Southeast porphyry Cu-Au deposit, theLepanto high sulfidation epithermal Cu-Au deposit, the Victoria intermediate sulfidation epithermal Au-Agvein deposit, the Teresa epithermal Au-Ag vein deposit, the Guinaoang porphyry Cu-Au deposit, and the Buakiand Palidan porphyry Cu-Au prospects, all having formed in a period of about 2 m.y., from ~3 Ma. The geologicunits include (1) a basement composed of Late Cretaceous to middle Miocene metavolcanic rocks andvolcaniclastic rocks; (2) the Miocene 12 to 13 Ma tonalitic Bagon intrusive complex; (3) the Pliocene, ~2.2 to1.8 Ma, Imbanguila dacite porphyry and pyroclastic rocks; and (4) postmineralization cover rocks, including the~1.2 to 1.0 Ma Bato dacite porphyry and pyroclastic rocks and the ~0.02 Ma Lapangan tuff.</p><p>Extensive advanced argillic alteration crops out for ~7 km along the unconformity between the basementrocks and the Imbanguila dacite formation and consists of quartz-alunite pyrophyllite or diaspore, with localzones of silicic alteration and a halo of dickite kaolinite. The alteration and its subhorizontal geometry indicatethat it is a lithocap or coalesced lithocaps. The northwest-striking portion is ~4 km long and hosts theLepanto enargite Au ore deposit, also controlled by the Lepanto fault. The Lepanto epithermal deposit isrelated to the underlying Far Southeast porphyry; the quartz-alunite alteration halo of Lepanto is contemporaneouswith the ~1.4 Ma potassic alteration of the porphyry. There are also silicic-advanced argillic alterationpatches ~600 m above the Far Southeast orebody at the present surface; these are interpreted to be perchedalteration. There is no systematic mineralogical or textural zoning in the Lepanto lithocap that indicates directionto the intrusive source. Most surface samples of the lithocap contain less than 50 ppb Au, despite manybeing less than a few hundred meters from underground Cu-Au ore.</p>This study found that several characteristics of the Lepanto lithocap change systematically with distancefrom the causative intrusion: The alunite absorption peak at ~1,480 nm in the short wavelength infrared(SWIR) spectrum shifts to higher wavelengths where the sample is closer to the intrusive center, due to higherNa and lower K content in the alunite; published experimental studies indicate that high Na/(Na + K) is relatedto higher formation temperature. High Ca alunite, including huangite, also occurs at locations proximal to theintrusive center. Alunite mineral composition analyzed by laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS) indicates that the Pb content decreases toward the intrusive center, whereas Sr, La,Sr/Pb, and La/Pb increase markedly. Whole-rock compositions, using only nonmineralized (taken as Cu <0.1wt% and Au <0.1 ppm) and alunite-bearing samples, show that Pb and Ag/Au, plus Hg and Ag, decrease towardthe intrusive center, and Sr/Pb and La/Pb ratios increase. Normalizing whole-rock Pb to the (Na + K) molalcontent produces a proxy for the alunite mineral composition, and this ratio provides the same indications asthe LA-ICP-MS analyses of alunite. The concealed Victoria epithermal veins consist of intermediate sulfidationmineralization on the southwest flank of the porphyry. The veins are not exposed, but their presence atdepth is indicated by subtle alteration (illite or interstratified illite and/or smectite or smectite + pyrite) andgeochemical (As, Se) anomalies at the surface. The anomalies are strongly dependent on erosion level; noanomalies were found where the surface is >~350 m above the upper extent of the veins. An airborne geophysicssurvey indicates that the Far Southeast orebody is associated with a wide zone of demagnetization dueto extensive magnetite-destructive phyllic alteration. Such low magnetic anomalies on the margin of a largelithocap elsewhere may deserve attention. The directional indicators and mineralization signatures found inthis study have the potential to indicate direction to the intrusive center during exploration of similar porphyryepithermaldistricts.