A paramagnetic lamellar polymer with a high semiconductivity

Yingjun Zhao, Maochun Hong, Yucang Liang, Rong Cao, Jiabao Weng, Shao‐Fang Lu, Wenjie Li

Chemical Communications · 2001 · 80 citations · 16 references

Concepts

Abstract

The polymer [Ni2(C4N2H3S)4] n with excellent electrical conductivity and ferromagnetic interaction between the nickel(II) centers has been prepared by the hydrothermal reaction of Ni(O2CMe)2 with pyrimidine-2-thiol in DMF–H2O; X-ray diffraction shows that the polymer possesses a lamellar structure formed from the conjunction system of pyrimidine rings and Ni(II) centers.

References

16