Concepedia

Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>Pb·tmeda] and [(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>Pb·4,4′-Me<sub>2</sub>bipy](tmeda = Me<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>NMe<sub>2</sub>, 4,4′-Me<sub>2</sub>bipy = 4,4′-dimethylbipyridine)

Michael A. Beswick, N.L. Cromhout, Christopher N. Harmer, Paul R. Raithby, Christopher A. Russell, Justin S. Smith, Alexander Steiner, Dominic S. Wright

Chemical Communications · 1996 · 19 citations · 13 references

DOI

Concepts

Abstract

The first Lewis-base adducts of a neutral p-block group metallocene, [(η-C5H5)2Pb·tmeda] 1 and [η-C5H5)2Pb·4,4′-Me2bipy] 2, result from the addition of tmeda and 4,4′-Me2bipy to [Pb(η-C5H5)2](1:1 equiv.); X-ray and solution studies reveal that the Lewis bases are only loosely associated to the PbII centres in these complexes.

References

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