Highly stereospecific SN2-type displacement of sulfinyl by hydroxy group under pummerer conditions

Synthesis of optically pure (R)- and (S)-α-trifluoromethyl-alanine

Pierfrancesco Bravo, Silvia C. Capelli, Stefano V. Meille et al. · Tetrahedron Asymmetry · 1994 · 76 citations

Natural Sciences, Chemistry, Organic Chemistry +1

New Versatile Fluorinated Chiral Building Blocks:  Synthesis and Reactivity of Optically Pure α-(Fluoroalkyl)-β-sulfinylenamines

Alberto Arnone, Pierfrancesco Bravo, Silvia C. Capelli et al. · The Journal of Organic Chemistry · 1996 · 60 citations

Natural Sciences, Chemistry, Medicinal Chemistry +14

Extreme Liquid Chromatographic Separation Effects in the Case of Diastereomeric Amides Containing Polar Substituents

Günter Helmchen, Günter Nill, Dieter Flockerzi et al. · Angewandte Chemie International Edition in English · 1979 · 57 citations

Pharmacy, Chemistry, Analytical Chemistry +14

Intramolecular capture of Pummerer rearrangement intermediates. 3. Interrupted Pummerer rearrangement: capture of tricoordinate sulfur species generated under Pummerer rearrangement conditions

Dallas K. Bates, R. Thomas Winters, Joseph A. Picard · The Journal of Organic Chemistry · 1992 · 50 citations

Natural Sciences, Chemistry, Analytical Chemistry +8

Synthesis of (2R, 3S)- or (2S, 3R)-2-amino-3-trifluoromethyl-3-hydroxyalkanoic acid derivatives (threonine and allo-threonine analogs) from enantiopure 4,4,4-trifluoro-3-hydroxybutanoic acid

Andrea Rolf Sting, Dieter Seebàch · Tetrahedron · 1996 · 41 citations

Natural Sciences, Chemistry, Medicinal Chemistry +6