Zeitschrift für Naturforschung B · 1977 · 13 citations · 0 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistrySolid-state ChemistryCoordination ChemistryCoordination NumberCrystal ChemistryCrystal SystemsCrystallographyTransition Metal ComplexesCation Coordination ChemistryCoordination Compound CharacterizationCoordination Geometry DeterminationCoordination Number DeterminationCrystal Structure RefinementEffective Coordination NumberOctahedral ComplexesOctahedral Coordination
Single crystals of Cu 2 OCl 2 were prepared and investigated by X-ray methods. Cu 2 OCl 2 crystallizes orthorhombic, space group D 2h 24 -Fddd (α = 969.9, b = 960.3, c = 746.2 pm). Cu 2+ has a distorted octahedral coordination. The JAHN-TELLER-Effect and effective coordination number are discussed.