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Formation and structure of a quadruply-iodo-bridged complex of dimolybdenum(<scp>III</scp>,<scp>IV</scp>), [(Cp*Mo)<sub>2</sub>(µ-l)<sub>4</sub>]l<sub>3</sub>(Cp*=η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>) and its reversible oxidation and reduction

Rinaldo Poli, John C. Gordon, Jahanvi U. Desai, Arnold L. Rheingold

Journal of the Chemical Society Chemical Communications · 1991 · 16 citations · 10 references

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Abstract

The mixed-valence quadruply-iodo-bridged [(Cp*Mo)2(µ-l)4]l3 has been crystallographically characterized; its cyclic voltammogram shows reversible oxidation and reduction processes and suggests that the [(Cp*Mo)2(µ-l)4]n+(n= 0,1,2) series of complexes is isostructural.

References

10

Diehloro(η<sup>5</sup> -cyclopentadienyl)chrom-Dimer / Dichloro(η<sup>5</sup>-cyclopentadienyl)chromium Dimer

Frank H. Köhler, Ren de Cao, Klaus Ackermann et al. · Zeitschrift für Naturforschung B · 1983 · 38 citations · Full text

, , +16

Reduction of tungsten complexes with primary phosphines and lithium dialkyl phosphides. X-ray crystal structures of [(Cp*WCl2)2·(t-Bu2PPt-Bu2)2], [(Cp*WCl4)(H2PPh)], [{(PhN)WCl2(PMe3)2} 2(μ-N2)] and trans-WCl4(H2Pt-Bu)2 (Cp* = η5-C5Me5)

C. Jeff Harlan, Richard A. Jones, Stefan U. Koschmieder et al. · Polyhedron · 1990 · 36 citations

, , +11

Studies on some π-cyclopentadienyl halides of molybdenum and tungsten

M. L. H. Green, W. Edward Lindsell · Journal of the Chemical Society A Inorganic Physical Theoretical · 1967 · 35 citations

, , +15

Synthesis of [Mo(η-C<sub>5</sub>H<sub>4</sub>Pr<sup>i</sup>)(PR<sub>3</sub>)<sub>2</sub>H<sub>3</sub>][R<sub>3</sub>= Me<sub>3</sub>or Me<sub>2</sub>Ph), [Mo(η-C<sub>5</sub>H<sub>4</sub>Pr<sup>i</sup>)(Pr<sup>i</sup><sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PPr<sup>i</sup><sub>2</sub>)H<sub>3</sub>], and analogues and their ability to catalyse the photoinduced hydrogen–deuterium exchange of carbon–hydrogen bonds; crystal structure of [{Mo(η-C<sub>5</sub>H<sub>4</sub>Pr<sup>i</sup>)(µ-Cl)<sub>2</sub>}<sub>2</sub>]

Peter D. Grebenik, Malcolm L. H. Green, Alejandro Izquierdo et al. · Journal of the Chemical Society Dalton Transactions · 1987 · 35 citations

, , +14

A new class of reactive, transition metal–metal doubly-bonded organodimetallic complexes: synthesis, structure, and reactivity of (η-C<sub>5</sub>Me<sub>4</sub>R)<sub>2</sub>Ta<sub>2</sub>(µ-X)<sub>4</sub>(R = Me, Et; X = Cl, Br)

Ching Ting, N. C. Baenziger, Louis Messerle · Journal of the Chemical Society Chemical Communications · 1988 · 33 citations

, , +12