Journal of the Chemical Society A Inorganic Physical Theoretical · 1967 · 35 citations · 0 references
Natural SciencesChemistryInorganic ChemistryMaterials ChemistrySpectroscopyCoordination ChemistryHalogen ChemistryInorganic SpectroscopyLanthanide ChemistryMetal-ligand BondingTransition Metal ComplexesElectronic Structure Of Metal ComplexesInfrared Absorption SpectraInfrared SpectraLanthanide Coordination ChemistryMetal-ligand Bonding AnalysisSpectroscopic Characterization Of Metal-ligand BondsVibrational Spectroscopy Of Metal-ligand Bonds
The preparation and properties of the complexes π-C5H5M(CO)2X3, where M = Mo or W, and X = Cl, Br, or I, are described. Their infrared spectra, and those of the complexes (π-C5H5)2MX2 and [(π-C5H5)2MX2]+HX2–, where M = Mo or W, and X = Br or I, are reported down to 70 cm.–1 and assignments to metal–halogen stretching frequencies are given.