<sup>1</sup>H and<sup>13</sup>C nuclear magnetic resonance spectra and X-ray crystal structure of [1-methyl-3-ethyl-(σ-1,3-h<sup>2</sup>,π-1,2,3-h<sup>3</sup>)-allyl]nonacarbonyltriruthenium: the allyl group as a five-electron donor - Concepedia

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<sup>1</sup>H and<sup>13</sup>C nuclear magnetic resonance spectra and X-ray crystal structure of [1-methyl-3-ethyl-(σ-1,3-h<sup>2</sup>,π-1,2,3-h<sup>3</sup>)-allyl]nonacarbonyltriruthenium: the allyl group as a five-electron donor

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1972

Year

Molly Evans, Michael B. Hursthouse, E. W. Randall, Edward Rosenberg, Luciano Milone, M.A. del Valle

Journal of the Chemical Society Chemical Communications

X-ray CrystallographyEngineeringMolecular BiologyOrganic ChemistryChemistrySpectra-structure CorrelationStructure ElucidationX-ray Crystal StructureOrganometallic CatalysisDiene LigandInorganic ChemistryFive-electron DonorCrystallographyInorganic SynthesisBiomolecular EngineeringSkeletal RearrangementAllyl GroupNatural SciencesCoordination ComplexMetal Hydride BondMolecular ComplexMain Group Chemistry

Abstract

The reaction of cis,trans- or trans,trans-hexa-2,4-diene and Ru3(CO)12 is shown, by 1H and 13C n.m.r. spectra and X-ray crystal structure to give a product in which the diene ligand has undergone a skeletal rearrangement producing a π-allyl group, a metal hydride bond, and two metal–carbon σ-bonds.