Interferometric study of rotational motion of hydrogen halides trapped in low-temperature matrices

A.J. Barnes, Justin Davies, H. E. Hallam, G. F. Scrimshaw, G. C. Hayward, R. C. Milward

Journal of the Chemical Society D Chemical Communications · 1969 · 15 citations · 0 references

Concepts

Abstract

The rotation of HCl and DCl in argon matrices at 20° K has been verified and the frequencies of the J= 1 â†�J= 0 transitions measured; rotation does not occur in a nitrogen matrix.